Synthesis and characterization of novel hyperbranched fluorescent polymers that can be precisely used for metal ion detection and quantification

Four novel hyperbranched polymers with 4 or 5 ring-closed rhodamine units in each were achieved through RAFT polymerization followed by modification with rhodamine moieties. The solubility, thermostability, and photophysical properties of the polymers were studied. The polymers showed high selectivity and sensitivity to Fe³⁺ among various metal ions in CH₃CN/H₂O (75/25, v/v) and could signal Fe³⁺ through multichannels: emerging a new absorption around 558 nm, over 30 nm fluorescence redshift and significant fluorescence enhancement (including 33–37 folds in intensity and 8.3–12.8 folds in quantum yield), accompanied by visual and fluorescent color changes. The polymers could be applied in the analysis of Fe³⁺ in real water samples. © 2020 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48933.     

页岩气地面设施建设技术探讨

本文根据页岩气地面建设生产需要,对页岩气开发的地面工艺技术、井场总平面布置、工艺设备及选材、仪表自控、通信、供配电等地面配套设施进行探讨,提出了适合页岩气开发的地面工艺技术方案,为页岩气地面设施建设提供了必要的技术借鉴。     

中国深空网VLBI相关处理器开发与应用

以中国深空网干涉测量信号处理中心建设为背景,论述了VLBI软相关处理系统的设计及初步实现。依据数据处理流程对软件模块化划分,一方面采用时间并行处理策略,将数据流按子积分周期分配给多个计算节点;一方面在相关计算节点内部应用多线程处理最大化提升效能。依托高性能集群系统,采用两级并行处理策略,实现了软件的设计开发,并在"嫦娥3号"(CE-3)任务中得到了首次应用。与事后精密轨道的比对分析表明,?DOR测量精度在1 ns量级,相当于90 nrad的角位置精度,等价于地月距离上37 m的位置误差。深空干涉测量信号处理中心VLBI软相关处理器有效支撑了CE-3的精密轨道测定。     

A Constitutive Equation of Thermoelasticity for Solid Materials

A new constitutive equation of thermoelasticity for crystals is presented based on the interatomic potential and solid mechanics at finite temperature. Using the new constitutive equation, the calculations for crystal copper and graphene are carried out under different loading paths at different temperatures. The calculated results are in good agreement with those of the previous thermoelasticity constitutive equation based on quantum mechanics, which clearly indicates that our new constitutive equation of thermoelasticity is correct. A lot of comparisons also show that the present theory is more concise and efficient than the previous thermal stress theory in the practical application.     

Hydroxypropylated microcrystalline pea starch: optimisation,functional characterisation

Pea starch (PS) appears to be very attractive for the peculiar physicochemical characteristics, which is used for the vermicelli, film‐forming material due to the high amylose content. The aim of this study was to optimise the hydroxypropylation technology parameters of the microcrystalline pea starch based on pea starch as a raw material, hydrochloric acid as an hydrolysis reagent, epoxy propane as an etherisation reagent by the Box–Behnken method. The thermal properties of hydroxypropylated microcrystalline pea starch were characterised by the thermogravimetric analyser and differential scanning calorimeter, respectively. Through the analysis of Design‐Expert software, the regression model and corresponding variances were obtained. In this case, the determination coefficient (R²) was 0.9631. This implied that 96.31% of the variation could be explained by the regression model. The best reaction conditions for preparing the hydroxypropylated microcrystalline pea starch were as follows: reaction temperature 40 °C, reaction time 16 h, amount of epoxy propane 14%, amount of sodium hydroxide 1.2% and amount of anhydrous sodium sulphate 12%. After the microcrystalline pea starch was hydroxypropylated, its peak temperature, melting enthalpy, temperature range of the endothermic peak increased, but its the thermal stability, onset temperature decreased.     

基于云平台的智能实验室远程监控系统

针对实验室管理中存在的安全问题,提出并设计了一种基于云平台的智能实验室远程监控系统.利用FRID技术对进出人员信息进行记录.在实验室内安装温度传感器和湿度传感器,把实验室内的环境数据上传至云平台,当温度传感器和湿度传感器检测到实验室环境参数异常时,云平台将实验室的数据信息及时反馈到当时正在值班的管理员的移动电话端上,提示实验室可能存安全隐患.烟雾传感器可以检测实验室的烟雾浓度和可燃气体.实验表明,系统可以在不同环境下正常工作,且运行可靠,反馈给云平台的数据和检测到的实验室环境参数准确,有助于提高实验室安全性.